Graft copolymer directed synthesis of micron-thick organized mesoporous TiO2 films for solid-state dye-sensitized solar cells.

نویسندگان

  • Sung Hoo Ahn
  • Jung Tae Park
  • Jong Kwan Koh
  • Dong Kyu Roh
  • Jong Hak Kim
چکیده

Micron thick, well-organized mesoporous TiO(2) films with high porosity and good connectivity were synthesized by templating an amphiphilic graft copolymer for solid-state dye-sensitized solar cells.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis of low-cost, rubbery amphiphilic comb-like copolymers and their use in the templated synthesis of mesoporous TiO2 films for solid-state dye-sensitized solar cells.

Low-cost, rubbery amphiphilic comb-like copolymers consisting of hydrophobic poly(lauryl methacrylate) (PLMA) and hydrophilic poly(oxyethylene methacrylate) (POEM) were synthesized via one-step free radical polymerization. The synthesis of PLMA-POEM copolymers was confirmed using Fourier transform infra-red spectroscopy (FT-IR), (1)H-nuclear magnetic resonance ((1)H-NMR) and gel permeation spec...

متن کامل

Mesoporous TiO2 Bragg Stack Templated by Graft Copolymer for Dye-sensitized Solar Cells

Organized mesoporous TiO₂ Bragg stacks (om-TiO₂ BS) consisting of alternating high and low refractive index organized mesoporous TiO₂ (om-TiO₂) films were prepared to enhance dye loading, light harvesting, electron transport, and electrolyte pore-infiltration in dye-sensitized solar cells (DSSCs). The om-TiO₂ films were synthesized via a sol-gel reaction using amphiphilic graft copolymers consi...

متن کامل

Structure control of organized mesoporous TiO2 films templated by graft copolymers for dye-sensitized solar cells.

Randomly microphase-separated graft copolymers have been self-reorganized so as to exhibit a micellar structure with excellent connectivity upon tuning the solvent affinity. These copolymers are used as a structure-directing agent for organized mesoporous TiO(2) films with no grain boundaries, leading to enhanced solar conversion efficiency of dye-sensitized solar cells.

متن کامل

Synthesis and Application of Two Organic Dyes Based on Indoline in Dye-Sensitized Solar Cells

In this paper we sensitized two new organic days dye 1 and dye 2 based on thioindigo with phenothiazine as the electron donor group. We used acrylic acid and cyanoacrylic acid as the electron acceptor anchoring group in dye 1 and dye 2 respectively. The proposed dyes were sensitized from phenothiazine as the starting material by standard reactions and characterized by different techniques such ...

متن کامل

Synthesis and characterization of Ag-doped TiO2 nanostructure and investigation of its application as dye-sensitized solar cell

A new strategy for enhancing the efficiency of TiO2 dye-sensitized solar cells (DSSCs) by doping foreign ion into TiO2 lattice via sol-gel process is reported. DSSCs are based on a semiconductor (i.e., TiO2), formed between a photo-sensitized anode and an electrolyte. In order to reach high conversion efficiency, it is important to increase the electron injection and optical absorption. One pro...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Chemical communications

دوره 47 20  شماره 

صفحات  -

تاریخ انتشار 2011